单斜BiVO4可见光催化降解甲基橙的形貌效应

以硝酸铋和偏钒酸铵为无机源,NaOH为pH值调节剂,三嵌段共聚物P123为表面活性剂,采用醇-水热法制备了多种形貌的单斜BiVO4.利用X射线衍射、N2吸脱附、扫描电子显微镜、X射线光电子能谱和紫外可见光漫反射等技术表征了其物化性质,并考察了这些BiVO4样品在可见光照射下降解甲基橙的催化活性.结果表明,表面活性剂和溶...     

Transition-metal-free mono- or dinitration of protected anilines

Abstract

An amide-assisted arene nitration is presented, and both mono- and dinitration of protected anilines could be effected by using NaNO₂ and NaNO₃ as the mono- and bisnitrating agents, respectively. This divergent synthesis is transition-metal- and acid-free, and features a broad substrate scope, low cost, and ortho–para selectivity.     

Anisotropic charge carrier transport of optoelectronic functional selenium-containing organic semiconductor materials

Organic semiconductors (OSCs) materials are currently under intense investigation because of their potential applications such as organic field-effect transistors, organic photovoltaic devices, and organic light-emitting diodes. Inspired by the selenization strategy can promote anisotropic charge carrier migration, and selenium-containing compounds have been proved to be promising materials as OSCs both for hole and electron transfer. Herein, we now explore the anisotropic transport properties of the series of selenium-containing compounds. For the compound containing Se Se bond, the Se Se bond will break when attaching an electron, thus those compounds cannot act as n-type OSCs. About the different isomer compounds with conjugated structure, the charge transfer will be affected by the stacking of the conjugated structures. The analysis of chemical structure and charge transfer property indicates that Se-containing materials are promising high-performance OSCs and might be used as p-type, n-type, or ambipolar OSCs. Furthermore, the symmetry of the selenium-containing OSCs will affect the type of OSCs. In addition, there is no direct relationship between the R groups with their performance, whether it or not as p-type OSCs or n-types. This work demonstrates the relationship between the optoelectronic function and structure of selenium-containing OSCs materials and hence paves the way to design and improve optoelectronic function of OSCs materials.     

Co9S8/MoS2异质结构的构筑及电催化析氢性能研究

利用前驱物形貌导向法,成功制备了Co₉S₈/MoS₂异质结构催化剂,该催化剂在碱性析氢反应（HER）中表现出优异的催化活性及稳定性,其在10 mA·cm^-2处的过电势仅为84 mV.通过X射线粉末衍射（XRD）、透射电子显微镜（TEM）、电子自旋共振（ESR）、拉曼光谱（Raman）、X射线光电子能谱（XPS）和同步辐射（XAFS）等表征,证明了CoS₂/MoS₂在H₂氛围下煅烧形成Co₉S₈/MoS₂的过程中,CoS₂中Co的配位模式从部分八面体向Co₉S₈中的四面体转变,这种转变可活化MoS₂的惰性平面,从而使其更有利于吸附H^*.除此之外,接触角数据表明：该催化剂具有良好的亲水性,有利于电解液渗透及气体分子的迅速扩散,从而促进HER反应速率.由于异质结构间具有强烈的相互作用,该催化剂可表现出良好的结构稳定性.本工作基于Co₉S₈/MoS₂异质结构的成功构筑及对其HER催化机理的充分探讨,为后续硫化物异质结及其在电催化中的应用提供了良好的思路和研究基础.     

Ash and Slag Waste as a Secondary Raw Material

In the process of industrial corporation activities a lot of waste, which pollutes the atmosphere, is generated, for example ash and slag. In Tomsk region, by estimates, ash stores occupy about 600 hectares, which contain about 25 million tons by weight. In Russian thermal power-stations ash disposal areas there are about 1.3 billion tons of ash, and only 10% of it is used. That is why this problem is topical enough. In this paper the scheme of producing ash ceramic bricks and complex ash and slag waste processing is shown. Besides, profitability of the project is presented.     

带交易费用的最优投资和比例再保险

研究了保险公司的最优投资和再保险问题.保险公司的盈余通过跳-扩散风险模型来模拟,可以把盈余的一部分投资到金融市场,金融市场由一个无风险资产和n个风险资产组成,并且保险公司还可以购买比例再保险;在买卖风险资产时,考虑了交易费用.通过随机控制的理论,获得了最优策略和值函数的显示解.     

Optimal investment with transaction costs based on exponential utility function: a parabolic double obstacle problem

This paper concerns optimal investment problem with proportional transaction costs and finite time horizon based on exponential utility function. Using a partial differential equation approach, we reveal that the problem is equivalent to a parabolic double obstacle problem involving two free boundaries that correspond to the optimal buying and selling policies. Numerical examples are obtained by the binomial method.     

基于特殊路径的局内车辆路径问题混合策略研究

针对运输途中遇到的某一或一系列无法预知的堵塞事件对决策者路径选择策略的影响,考虑堵塞只发生在一条特殊路径上且可恢复的情况,采用局内竞争分析的思想,建立了局内车辆路径问题的数学模型,对车辆到达堵塞点时堵塞恢复时间未知这一情形下的路径选择问题,提出了两种混合策略,给出了相应的竞争比,并对其竞争性能进行了理论分析。     

科技保险中项目投资损失保险投保比例优化决策

针对我国科技保险第二批推行险种--项目投资损失保险,以科技企业为研究主体,综合考虑其期望利润和科技风险(方差),构建了投保比例模型.在对武汉市迪源光电科技有限公司投保科技保险的具体案例中,运用线性不等式组的旋转算法进行求解,计算出企业在项目组合投资中如何优化各项投保比例,使其以最小的风险承担得到最大的期望利润.     

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与经典Cramer-Lundberg风险模型中保费收取过程 是时间的线性函数不同, 我们考虑聚合的保费收取过程是复合Poisson过程, 研究了在此模型下的常数分红策略问题. Dickson和Waters,(2004)指出在破产发生时, 股东还应有责任偿付破产时的赤字. 因此, 在本文中考虑的最优准则是最大化破产发生前的分红折现值与破产发生时赤字的差的期望. 做为例子, 当个体保费收取额和索赔额均为指数分布时, 给出了计算分红障碍的条件